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Important compounds: K2Cr2O7, KMnO4

d-Block Elements (Transition Metals) · Chemistry

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KMnO₄ oxidises Fe²⁺ differently in acid vs alkaline medium. Show both. Step 1: Acid: MnO₄⁻ + 8H⁺ + 5e⁻ → Mn²⁺ + 4H₂O (purple → colourless). Step 2: 5Fe²⁺ → 5Fe³⁺ + 5e⁻. Overall: MnO₄⁻ + 5Fe²⁺ + 8H⁺ → Mn²⁺ + 5Fe³⁺ + 4H₂O. Step 3: Alkaline: MnO₄⁻ + e⁻ → MnO₄²⁻ (purple → green manganate). Step 4: Medium decides the product — that's why titrations specify conditions!

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